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Sharma, Arun Kumar
- Removal of Sulphur Dioxide from Exhaust Sulphurous Flue Gases at Shree Cement Ltd., Beawar for Environment Cleaning
Abstract Views :154 |
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Authors
Affiliations
1 Department of Chemistry, S.D. Government College, Beawar-305 901, Rajasthan, IN
1 Department of Chemistry, S.D. Government College, Beawar-305 901, Rajasthan, IN
Source
Nature Environment and Pollution Technology, Vol 9, No 3 (2010), Pagination: 559-562Abstract
Laboratory studies were conducted to know about the effect of pH of sodium hydroxide solution and its temperature for absorption of SO2 contained in flue gases. it was found that the pH of the solution should be alkaline for good absorption of SO2. Because of the acidic nature of SO2, the reaction is restricted in acidic solution. and maximum absorption of SO2 was found in temperature range between 20-25°C. At higher temperature reversible reaction may take place and partially formed product may be changed back into initial reactants.Keywords
Flue Gases, Sulphur Dioxide, Desulphurization, Shree Cement Ltd.- Ultrasonic Studies of Cu (II) Soaps Derived from Groundnut and Seasame Oils
Abstract Views :193 |
PDF Views:3
Authors
Affiliations
1 Department of Chemistry, S.P.C. Govt. College Ajmer-305001, IN
2 Department of Chemistyr, S.D. Govt. College Beawar-305901, IN
1 Department of Chemistry, S.P.C. Govt. College Ajmer-305001, IN
2 Department of Chemistyr, S.D. Govt. College Beawar-305901, IN
Source
Journal of Pure and Applied Ultrasonics, Vol 39, No 3 (2017), Pagination: 92-99Abstract
Ultrasonic speed have been measured in pure and binary mixtures containing copper soaps derived from groundnut and sesame oils in 20 % and 40% methanol benzene mixture. From these values, the specific acoustic impedance, adiabatic compressibility, intermolecular free length, apparent molar compressibility, molar sound velocity, primary solvation number have been calculated. The results have been fitted to Masson equation. The results have been explained on the basis of intermolecular interactions.Keywords
Copper Soaps, Methanol, Groundnut Oil, Sesame Oil, Ultrasonic Speed.References
- Pawar N.R. and Chimankar O.P., Comparative study of ultrasonic absorption and relaxation behavior of polar solute and non-polar solvent, J. Pure Appl. Ultrason. 34 (2012) 49-52.
- Sivakumar V., Verma R.V., Rao P.G. and Swaminathan G., Studies on the use of power ultrasound in solid liquid myrobal an extraction process. J. Clean Prod. 15 (2007) 1813-1818.
- Nath G., Ultrasonic Study of Binary Mixture of Acetone with Bromo benzene and Chloro benzene at Different Frequencies, Chem. Sci. Trans. 1(3) (2012) 516-521.
- Moharatha D., Talukdar M., Roy G.S. and Dash U.N., Evaluation of acoustic parameters of halides of alkali metals and Ammonium in aqueous and aqueous Dextran solutions at 298.15K, Researcher 3 (2011) 6-12.
- Palani R. and Balakrishnan S., Acoustical properties of ternary mixtures of 1-alkanols in di-isopropyl ether and 2, 2, 2-trifluoroethanol mixed solvent, Indian J. Pure Appl. Phys. 48 (2010) 644-650.
- Singh G. and Banipal T.S., Partial molar adiabatic compressibilities and viscosities of some amino acids in aqueous glycerol solutions at 298.15K, Indian J. Chem. 47A (2008) 1355.
- Sharma R., Bhutra R. and Khan S., Micellar Behaviour of Copper Surfactants Derived from Fresh (Untreated) Sesame Oil and Used (Treated at High Temperature) Sesame Oil, Tenside Surf Det. 47 106-112.
- Das J., Dash K., Swain S.K. and Swain N., Ultrasonic investigation in a polar-polar system, methyl-Isobutyl Ketone and aliphatic alcohols, J. Mol. Liquids. 81 (1999) 163-179.
- Ranganayakulu S.V., Reddy C.S. and Reddy D.L., Ultrasonic studies of the binary mixtures of ethyl acetateand cresols-application of Kosower and Dimroth treatments, Mat. Chem. Phys. 90 (2005) 213-216.
- Kanhekar S.R., Pravina P. and Govind K.B., Thermodynamic properties of electrolytes in aqueous solutions of glycine at different temperatures, Indian J. Pure Appl. Phys. 48 (2010) 95-99.
- Fort R.J. and Moore W.R., Adiabatic compressibilities of binary liquid mixtures, Trans. Faraday Soc. 61 (1965) 2102-2111.
- Banipal P.K. Chakal A.K. and Banipal T.S., Studies on volumetric properties of some saccharides in aqueous potassium chloride solutions over temperature range (288.15-318.15 K), J. Chem. Thermodynamic. 41 (2009) 452-483.
- Savaroglu G. and Ozdemir M., Apparent molar volume and apparent molar isentropic compressibility of glycerol in fructose water at different temperature, J. Mol. Liquids. 137 (2008) 51-57.
- Syal V.K., Chauhan S. and Gautam R., Ultrasonic velocity measurements of carbohydrates in binarymixtures of DMSO + H2O at 25°C, Ultrasonics. 36 (1998) 619621.
- Ali A., Hyder S. and Nain A.K., Intermolecular and ion solvent interaction of sodium iodide and potassium iodide in dimethyl formamide + I-propanol mixtures at 303K, J. Pure Appl. Ultrason. 21 (1999) 127-131.
- Punitha S. and Uvarani R., Physico-chemical studies on some saccharides in aqueous cellulose solutions at different temperatures- Acoustical and FTIR analysis J. Saudi Chem. Soc. 18 (2014) 657-665.
- Kagathara V.M., Sanariya M.R. and Parsania P.H., Sound velocity and molecular interaction studies on chloroepoxy resins solutions at 30°C, Eur. Polym. J. 36 (2000) 2371-2374.
- Dash A.K. and Paikaray R., Acoustical study on ternary mixture of dimethyl acetamide (DMAC) in diethyl ether and isobutyl methyl ketone at different frequencies, Phys.Chem. Liq. 51(6) (2013) 749-763.
- Singh S. and Bahadur I., Density and speed of sound of 1-ethyl-3-methylimidazolium ethylsulphate with acetic or propionic acid at different temperatures, J. Mol. Liq. 199 (2014) 518-523.
- Jahagirdar B.V., Arbad. B.R., Walvekar. A.A., Shankarwer A.G. and Lande M., Studies in partial molar volumes, partial molar compressibilities and viscosity Bcoefficients of caffeine in water at four temperatures, J. mol. liq. 85 (2000) 361-373.
- Production of Protease from Soil Fungi by Submerged Fermentation
Abstract Views :565 |
PDF Views:173
Authors
Affiliations
1 Department of Bioscience and Biotechnology, Banasthali University, Rajasthan, IN
2 Department of Biochemical Engineering, Bipin Tripathi Kumaon Institute of Technology, Dwarahat, Uttrakhand, IN
1 Department of Bioscience and Biotechnology, Banasthali University, Rajasthan, IN
2 Department of Biochemical Engineering, Bipin Tripathi Kumaon Institute of Technology, Dwarahat, Uttrakhand, IN
Source
SMU Medical Journal, Vol 4, No 2 (2017), Pagination: 211-221Abstract
The demand of proteases is increasing regularly because of their numerous applications in the biotechnological industries. It promotes isolation and identification of potent protease producing fungi from soil samples. Therefore, the objective of the present investigation was to screen soil fungi in submerged fermentation (SmF) for detection of hyperproducer isolate and production of protease in SmF. Fungal strains from three diverse soil samples were isolated on potato dextrose agar (PDA) plates by serial dilution agar plate technique, purified by point inoculation and twelve isolates utilized for production of extracellular protease in SmF. Results were examined both in terms of protease activity and specific activity. Among all 12 fungal strains, isolate S2St1 (isolated from medicinal garden soil) exhibited maximum activity of protease (256.63 ± 3.18 U/ml/min) at 72 h of incubation. Isolate S2St1 was identified as potent producer of protease in SmF. Further this isolate can be used for production of large quantity of protease in SmF within very short time period of 3 days.Keywords
Proteases, Potato Dextrose Agar, Fungi, Soil Samples, Submerged Fermentation.References
- Gupta, R., Beg, QK. and Lorenz, P (2002) Bacterial alkaline proteases: molecular approaches and industrial applications. Appl Microbiol Biotechnol. 59, 15-32.
- Lin, Y. and Tanaka, S (2006) Ethanol fermentation from biomass resources: current state and prospects. Appl. Microbiol Biotechnol. 69, 627-642.
- Brijwani, K., Oberoi, HS. and Vadlani, PV (2010) Production of a cellulolytic enzyme system in mixed-culture solid-state fermentation of soybean hulls supplemented with wheat bran. Process Biochem. 45, 120-128.
- Krem, MM. and Di Cera, E (2001) Molecular markers of serine protease evolution. The EMBO Journal. 20, 3036-3045.
- da silva, RR., Caetano, RC., Okamoto, DN., de Oliveira, LC., Bertolin, TC., Juliano, MA., de Oliveira, AH., Rosae, JC. and Cabral, H (2014) The identification and biochemical properties of the catalytic specificity of a serine peptidase secreted by Aspergillus fumigatus Fresenius. Protein Pept Lett. 21, 663-671.
- Halabi, N., Rivoire, O., Leibler, S., and Ranganathan, R (2009) Protein sectors: evolutionary units of three-dimensional structure. Cell. 138, 774-786.
- Souza, PM., Bittencourt, MLA., Caprara, CC., Freitas, M., Almeida, RPC., Silveira, D., Fonseca, YM., Filho, EXF., Junior, AP., and Magalhaes, PO (2015) A biotechnology perspective of fungal proteases. Braz J Microbiol. 46, 337-346.
- Saran, S., Isar, J. and Saxena, RK (2007) A modified method for the detection of microbial proteases on agar plates using tannic acid. J Biochem Biophys Methods. 70, 697-699.
- Zambare, V., Nilegaonkar, S. and Kanekar, PA (2011) Novel extracellular protease from Pseudomonas aeruginosa MCM B-327: enzyme production and its partial characterization. N Biotechnol. 28, 173-181.
- Anitha, TS. and Palanivelu, P (2013) Purification and characterization of an extracellular keratinolytic protease from a new isolate of Aspergillus parasiticus. Protein Expr Purif. 88, 214-220.
- Sandhya, C., Sumantha, A., Szakacs, G. and Pandey, A (2005) Comparative evaluation of neutral protease production by Aspergillus oryzae in submerged and solid-state fermentation. Process Biochem. 40, 2689-2694.
- Edwinoliver, NG., Thirunavukarasu, K., Naidu, RB., Gowthaman, MK., Kambe, TN. and Kamini, NR (2010) Scale up of a novel tri-substrate fermentation for enhanced production of Aspergillus niger lipase for tallow hydrolysis. Bioresour Technol. 101, 6791-6796.
- Waksman, SA (1922) A Method for Counting the Number of Fungi in the Soil. J Bacteriol. 7, 339-341.
- Sharma, AK., Sharma, V., Saxena, J., Yadav, B., Alam, A. and Prakash, A (2015) Effect of culture conditions on protease production and activity of protease from soil borne fungi. International Journal of Scientific Research in Environmental Sciences. 3, 0411-0419.
- Sharma, AK., Sharma, V., Saxena, J., Yadav, B., Alam, A. and Prakash, A (2015) Isolation and screening of extracellular protease enzyme from bacterial and fungal isolates of soil. International Journal of Scientific Research in Environmental Sciences. 3, 0334-0340.
- Josephine, FS., Ramya, VS., Neelam, D., Suresh, BG., Siddalingeshwara, KG., Venugopal, N. and Vishwanatha, TJ (2012) Isolation, production and characterization of protease from Bacillus sp. Isolated from soil sample. J Microbiol Biotechnol Res. 2, 163-168.
- Lowry, OH, Rosenbrough, NJ., Farr, AL. and Randall, A (1951) Protein measurement with the folin phenol reagent. J Biol Chem. 193, 265-275.
- Tsuchida, O., Yamagota, Y., Ishizuka, J., Arai, J., Yamada, J., Takeuchi, M. and Ichishima, E (1986) An alkaline protease of an alkalophilic Bacillus sp. Curr. Microbiol.14, 7-12.
- Yezli, W., Zebboudj, N., Karkachi, NE., Kihal, M. and Henni, JE (2015) Influence of two substrates (casein and glucose) on mycelia growth and dosage of proteolytic activity of Fusarium oxysporum f. sp. albedinis (Foa). Int J Biosc. 6, 115-125.
- Anand, K (2016) Fungal Protease Production by Aspergillus niger and Aspergillus flavus Using Rice Bran as the Substrate. Acad J Agric Res. 4, 333-338.
- Oseni, OA (2011) Production of Microbial Protease from Selected Soil Fungal Isolates. Nig J Biotech. 23, 28-34.
- Ali, SS. and Vidhale, NN (2013) Protease Production by Fusarium oxysporum in SolidState Fermentation Using Rice Bran. Am J Microbiol Res. 1, 45-47.
- Irfan, M., Rauf, A., Syed, Q., Nadeem, M. and Baig, S (2011) Exploitation of Different Agro-residues for Acid protease Production by Rhizopus sp. in Koji Fermentation. Int J Agro Vet Med Sci. 5, 43-53.
- Kamath, P., Subrahmanyam, VM., Rao, JV. and Raj, PV (2010) Optimization of Cultural Conditions for Protease Production by a Fungal Species. Indian J Pharm Sci. 72, 161-166.
- Muthulakshmi, C., Duraisamy, G., Dugganaboyana, G. K., Ganesan, R., Manokaran, K. and Chandrasekar, U (2011) Production, Purification and Characterization of Protease by Aspergillus flavus under Solid State Fermentation. Jordan J Biol Sci. 4, 137-148.
- Optimization of Protease Production from Wild and Mutant Strains of Aspergillus sp. under Submerged Fermentation
Abstract Views :529 |
PDF Views:164
Authors
Affiliations
1 Department of Bioscience and Biotechnology, Banasthali University, Rajasthan, IN
2 Department of Biochemical Engineering, Bipin Tripathi Kumaon Institute of Technology, Dwarahat, Uttrakhand, IN
1 Department of Bioscience and Biotechnology, Banasthali University, Rajasthan, IN
2 Department of Biochemical Engineering, Bipin Tripathi Kumaon Institute of Technology, Dwarahat, Uttrakhand, IN
Source
SMU Medical Journal, Vol 4, No 2 (2017), Pagination: 234-247Abstract
Proteases are one of the most significant groups of commercial enzymes and contribute 60% of the world enzyme market. The choice of proteases is the microbial proteases due to their versatility, stability and distinctive properties. Today, microbial proteases are utilized in various industries viz., meat processing, ripening of cheese, detergents, textile, recovery of silver from photographic image etc. Therefore, the present study was undertaken to increase the protease production from wild and mutagenic strain of Aspergillus sp. Wild and mutagenic strain of proteolytic soil fungus Aspergillus sp. was used for optimization study. Different parameters (nitrogen, carbon sources, temperature, pH and incubation time) were optimized in submerged fermentation (SmF) for enhanced protease production. Wild strain demonstrated highest protease activity at pH 10.0 after 48 h of incubation at 37 °C in the medium containing glucose as carbon source and yeast extract as nitrogen source whereas optimum protease activity from mutagenic strain was found at pH 10.0 after 94 h of incubation at 37 °C in the medium containing fructose as carbon source and peptone as nitrogen source. Protease production was increased from wild and mutagenic strain of Aspergillus sp. after parameters optimization in SmF.Keywords
Optimization, Protease Activity, Aspergillus sp., Carbon Source, Temperature, pH.References
- Negi, S. and Banerjee, R (2006) Optimization of amylase and protease production from Aspergillus awamori in single bioreactor through EVOP factorial design technique. Food Technol Biotechnol. 44, 257-261.
- Rani, K., Rana, R. and Datt, S (2012) Review on latest overview of proteases. Int J Curr Life Sci 2, 12-18.
- Rocha, MV., Romanini, D., Nerli, BB. and Tubio, G (2012) Pancreatic serine protease extraction by affinity partition using a free triazine dye. Int J Biol Macromol. 50, 303-309.
- Gupta, R., Beg, QK. and Lorenz, P (2002) Bacterial alkaline proteases: molecular approaches and industrial applications. Appl Microbiol Biotechnol. 59:15-32.
- Rao, MB., Tanksale, AM., Ghatge, MS. and Deshpande, VV (1998) Molecular and biotechnological aspects of microbial proteases. Microbiol Mol Biol Rev. 62, 597-635.
- Nirmal, NP., Shankar, S. and Laxman, RS (2011) Fungal proteases: an overview. Int J Biotech Biosci. 1, 1-40.
- Laxman, RS., Sonawane, AP., More, SV., Rao, BS., Rele, MV., Jogdand, VV., Deshpande, VV. and Rao, MB (2005) Optimization and scale up of production of alkaline protease from Conidiobolus coronatus. Process Biochem. 40, 3152-3158.
- Shankar, S., Rao, M. and Laxman, SR (2011) Purification and characterization of an alkaline protease by a new strain of Beauveria sp. Process Biochem. 46, 579-585.
- Wu, TY., Mohammad, AW., Jahim, JM. and Anuar, N (2006) Investigations on protease production by a wild-type Aspergillus terreus strain using diluted retentate of pre-filtered palm oil mill effluent (POME) as substrate. Enzyme Microb Tech. 39, 1223-1229.
- Farley, PC. and Ikasari, L (1992) Regulation of the secretion of Rhizopus Oligosporus extracellular carboxyl proteinase. J Gen Microbiol. 138, 2539-2544.
- Fan-Ching, Y. and Lin, IH (1998) Production of acid protease using thin stillage from a rice-spirit distillery by Aspergillus niger. Enzyme Microb Technol. 23, 397-402.
- Chrzanowska, J., Kolaczkowska, M. and Polanowski, A (1993) Production of exocellular proteolytic enzymes by various species of Penicillium. Enzyme Microb Technol. 15, 140-143.
- Aleksieva, P. and Peeva, L (2000) Investigation of acid proteinase biosynthesis by the fungus Humicola lutea 120-5 in an airlift bioreactor. Enzyme Microb Technol. 26, 402-405.
- Lasure, LL (1980) Regulation of extracellular acid protease in Mucor miehei. Mycologia, 72, 483-493.
- Rao, MB., Tanksale, AM., Ghatge, MS. and Deshpande, VV (1998) Molecular and biotechnological aspects of microbial proteases. Microbiol Mol Biol Rev. 62, 597-635.
- Tsuchida, O., Yamagota, Y., Ishizuka, J., Arai, J., Yamada, J., Takeuchi, M. and Ichishima, E (1986) An alkaline protease of an alkalophilic Bacillus sp. Curr Microbiol. 14, 7-12.
- Rajput, K., Chanyal, S. and Agrawal, PK. Optimization of protease production by endophytic fungus, Alternaria alternata isolated from gymnosperm tree- cupressus torulosa d.don. World J Pharma Pharm Sci. 5, 1034-1054, 2016.
- Srinubabu, G., Lokeswari, N. and Jayaraju, K (2007) Screening of Nutritional Parameters for the Production of Protease from Aspergillus Oryzae. E-Journal of Chemistry. 4, 208-215.
- Venkat Kumar, S., Rao, A. and Nazareth, JR (2015) Screening, media optimization and partial purification of protease by Trichosporon japonicum vitvk1. International Journal of Pharmacy and Pharmaceutical Sciences. 7, 187-191.
- Muthukrishnan, S. and Mukilarasi, K (2016) Industrial Important Protease Screening and Optimization from Micro-Fungal Isoltaes of Ayyanar Falls Forest Samples, Rajapalalyam. World Appl Sci J. 34, 343-347.
- Sharma, AK., Sharma, V., Saxena, J., Yadav, B., Alam, A. and Prakash, A. (2015) Effect of Culture Conditions on Protease Production and Activity of Protease from Soil Borne Fungi. International Journal of Scientific Research in Environmental Science. 3, 0411-0419.
- Zaferanloo, B., Quang, TD., Daumoo, S., Ghorbani, MM. and Palombo, EA (2014) Optimization of protease production by endophytic fungus, Alternaria alternata, isolated from an Australian native plant. World J Microbiol Biotechnol. 30, 1755-1762.
- Milala, MA., Jatau, IA. and Abdulrahman, AA (2016) Production and Optimization of Protease from Aspergillus niger and Bacillus subtilis using Response Surface Methodology. IOSR J Biotechnol Biochem. 2, 01-07.
- Studies of Ultrasonic and Acoustic Parameters of Cu (II) Surfactant of Fresh and Treated Sesame and Soyabean Oils at High Temperature for Different Time
Abstract Views :167 |
PDF Views:0
Authors
Affiliations
1 Department of Chemistry, Rajesh Pilot Government Polytechnic College, Dausa-303303, IN
2 S.P.C. Government College, Ajmer-305001, IN
3 Government P.G. College, Jhalawar-326001, IN
1 Department of Chemistry, Rajesh Pilot Government Polytechnic College, Dausa-303303, IN
2 S.P.C. Government College, Ajmer-305001, IN
3 Government P.G. College, Jhalawar-326001, IN
Source
Journal of Pure and Applied Ultrasonics, Vol 40, No 2 (2018), Pagination: 46-51Abstract
Colloid chemical behavior and micellar characteristics of Cu (II) soaps derived from sesame and soyabean oils, (fresh oils and treated for 15 and 60 min.) at high temperature in benzene have been investigated and verified by ultrasonic velocity measurement. From these values, the specific acoustic impedance Z, adiabatic compressibility βad, intermolecular free length Lf, apparent molar compressibility Øk, molar sound velocity R, primary solvation number Sn have been calculated. The results have been analyzed in terms of Masson's equation. The results have been explained on the basis of solute-solvent interactions. The decrease in β and Lf with increasing concentration of the complex is indicating that there is sufficient solute- solvent interaction due to which micellar alignment is considerably affected.Keywords
Copper Surfactants, Benzene, Sesame Oil, Soyabean Oil, Ultrasonic, Solute-Solvent Interaction.References
- Saxena M., Sharma R. and Sharma A.K., Micellar Features of Cu (II) surfactants derived from edible oils "ISBN 978-620-2-01906-4" LAP Lambert Academic Publishing Germany (2017).
- Sharma A.K., Saxena M. and Sharma R., Synthesis, spectroscopic and fungicidal studies of Cu (II) soaps derived from groundnut and sesame oils and their urea complexes, Bulletin of Pure and Applied Sciences, 36(2) (2017) 26-37.
- Khan S., Sharma R. and Sharma A.K., Acoustic studies and other acoustic parameters of Cu(II) soap derived from nonedible neem oil (azadirecta indica), in non-aqueous media at 298.15, Acta Ac united Ac. 104 (2018) 277-283
- Sharma A.K., Saxena M. and Sharma R., Synthesis, spectroscopic and biocidal activities of environmentally safe Agrochemicals, J. Biochem. Tech. 7(3) (2018) 1139-1147.
- Tank P., Sharma R. and Sharma A.K., Studies of Ultrasonic and acoustic parameters of complexes derived from Copper (II) surfactant of mustard oil with N and S atoms containing ligands in non-aqueous media (benzene) at 303.15 K. J. Acous. Soc. Ind. 44(2) (2017) 87-99.
- Bhutra R., Sharma R. and Sharma, A.K., Viscometric and CMC studies of Cu(II) surfactants derived from untreated and treated groundnut and mustard oils in non-aqueous solvent at 298.15 K, J. Inst. Chemists. 90 (2017) 29-47.
- Sharma S., Sharma R. and Sharma A.K., Synthesis, Characterization, and thermal degradation of Cu (II) Surfactants for sustainable green chem, Asian J. Green Chem. 2(2) (2017) 129-140.
- Sharma S., Sharma R., Heda L.C. and Sharma, A.K., Kinetic parameters and photo degradation studies of copper soap derived from soybean oil using ZnO as a Photo catalyst in solid and solution Phase, J. Inst. Chemists. 89(4) (2017) 119-136.
- Tank P., Sharma R. and Sharma A.K., A pharmaceutical approach and antifungal activities of copper Soaps with their N and S donor complexes derived from mustard and soyabean oils, Glob. J. Pharmaceu. Sci. 3(4) (2017) GJPPS.MS.ID.555619.
- Khan S., Sharma R. and Sharma A.K., Ultrasonic studies of Cu (II) Soap derived from seed oil of Pongamia pinnata (Karanj), in non-aqueous binary and ternary systems at 298.15K. Malaysian J. Chem. 19(2) (2017) 99-110.
- Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of copper soaps urea complexes derived from mustard and soyabean oils. J. Phy. Sci. (2018) (Accepted).
- Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of Cu (II) soaps derived from mustard and soybean oils. J. Pure Appl. Ultrason, 39(3) (2017) 92-99.
- Tank P., Sharma R. and Sharma A.K., Micellar features and various interactions of copper soap complexes derived from edible mustard oil in benzene at 303.15 K. Curr. Phy. Chem. 8(1) (2018) 46-57.
- Sharma R. and Sharma A.K., Natural edible oils: comparative health aspects of sesame, coconut, mustard (rape seed) and groundnut (peanut) a biomedical approach, Biomed. J. Sci. Tech. Res. 1(5) (2017) BJSTR.MS.ID.000441.
- Tank P., Sharma A.K. and Sharma R., Thermal behaviour and kinetics of copper (II) soaps and complexes derived from mustard and soyabean oil, J. Anal. Pharm. Res. 4(2) (2017) 1-5.
- Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of Cu (II) Soaps derived from Groundnut and Sesame oils, Tenside. Surf. Det. 55(2) (2018) 127-134.
- Bhutra R., Sharma R. and Sharma A.K., Synthesis, Characterization and fungicidal activities of Cu (II) surfactants derived from groundnut and mustard oils treated at high temperatures, J. Inst. Chemists. 90(3) (2018) 66-80.
- Sharma A.K., Sharma R. and Saxena M., Biomedical and antifungal application of Cu(II) soaps and its urea complexes derived from various oils, Open Access J. Trans. Med. Res. 2(2) (2018) 40-43.
- Sharma A.K., Sharma S. and Sharma R., Thermal degradation of Cu (II) metallic soaps and their Characterizations. A pharmaceutical application, Chro. Phar Sci., 1(5) (2017) 312-319.
- Sharma A.K., Saxena M. and Sharma R., Acoustic studies of copper Soap-urea complexes derived from groundnut and seasam oils. J. Phy. Studies, 21(4) (2017) 4601-6.
- Acoustic Parameters and Studies of Complexes Containing Copper Surfactants with Substituted 2-Amino-6-Chloro Benzothiazole
Abstract Views :252 |
PDF Views:0
Authors
Affiliations
1 Department of Chemistry, Government P.G. College, Jhalawar-326001, IN
2 Department of Chemistry, S.P.C. Government College, Ajmer-305001, IN
1 Department of Chemistry, Government P.G. College, Jhalawar-326001, IN
2 Department of Chemistry, S.P.C. Government College, Ajmer-305001, IN
Source
Journal of Pure and Applied Ultrasonics, Vol 41, No 3 (2019), Pagination: 63-68Abstract
Ultrasonic speed and density parameters have been measured in binary and ternary systems containing complexes of copper surfactants (caprylate, caprate, and laurate) with substituted 2-amino-6-chloro benzothiazole in 80% and 40% benzene-methanol mixture at constant temperature using thermostatic water bath. From these values, the specific acoustic impedance Z, adiabatic compressibility , intermolecular free length Lf, apparent molar compressibility φk, have been calculated. The results have been explained on the basis of intermolecular interactions and indicate that there is sufficient solute-solvent interaction due to which micellar alignment is considerably affected. The decrease in adiabatic compressibility β and intermolecular free length Lf of the copper surfactant complex solution with increasing concentration of copper surfactant complex in 80% and 40% benzene methanol has been observed which suggest that the non-polar long chains or lypophilic segment of the molecule in the solution are enveloped by a layer of solvent molecules bound and oriented towards lypophilic end. The orientation of the solvent molecules around the solutes may be due to the influence of electrostatic fields of solutes and results in the increase in the internal pressure and in lowering the compressibility of the solution i.e. the solution becomes harder to compress.Keywords
Acoustic Parameters, Benzothiazole, Copper, Surfactants.References
- Fort R.J. and Moore W.R., Adiabatic compressibilities of binary liquid mixtures, Trans. Faraday Soc. 61 (1965) 2102-2111.
- Bhutra R., Sharma R. and Sharma A.K., Studies of ultrasonic and acoustic parameter of copper (II) surfactants of groundnut and soyabean oils treated at different temperatures. J Acoust. Soc. India, 25(1) (2018) 42-52.
- Banipal P.K., Chakal A.K. and Banipal T.S., Studies on volumetric properties of some saccharides in aqueous potassium chloride solutions over temperature range (288.15-318.15 K), J. Chem. Thermodynamic. 41 (2009) 452-483.
- Khan S., Sharma R. and Sharma A.K., Acoustic studies and other acoustic parameters of Cu (II) soap derived from nonedible Neem oil (azadirectaindica), in non-aqueous media at 298.15, Acta Ac united Acust. 104 (2018) 277-283.
- Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of Cu (II) Soaps derived from groundnut and Sesame oils, Tenside. Surf. Det. 55(2) (2018) 127-134.
- Savaroglu G. and Ozdemir M., Apparent molar volume and apparent molar isentropic compressibility of glycerol in fructose water at different temperature, J. Mol. Liq. 137 (2008) 51-57.
- Tank P., Sharma R. and Sharma A.K., Studies of Ultrasonic and acoustic parameters of complexes derived from copper (II) surfactant of mustard oil with N and S atoms containing ligands in non-aqueous media (benzene) at 303.15 K. J. Acous. Soc. India 44(2) (2017) 87-99.
- Bhutra R., Sharma R. and Sharma A.K., Studies of ultrasonic and acoustic parameters of copper (II) surfactant of sesame and soyabean oils treated at different temperatures. J. Pure Appl. Ultrason. 40 (2018) 46-51.
- Khan S., Sharma R. and Sharma A.K., Ultrasonic studies of Cu(II) soap derived from seed oil of pongamiapinnata (Karanj), in non-aqueous binary and ternary systems at 298.15K. Malaysian J. Chem. 19(2) (2017) 99-110.
- Sharma R., Gangwal A. and Sharma A.K., Copper soap-complexes: micellar and biological analysis LAP LAMBERT Academic Publishing: Germany (2018).
- Syal V.K., Chauhan S. and Gautam R., Ultrasonic velocity measurements of carbohydrates in binarymixtures of DMSO + H2O at 25°C, Ultrasonics 36 (1998) 619-621.
- Ali A., Hyder S. and Nain A.K., Intermolecular and ion solvent interaction of sodium iodide and potassium iodide in dimethyl formamide + I-propanol mixtures at 303K, J. Pure Appl. Ultrason. 21(1999) 127-131.
- Sharma A.K., Saxena M. and Sharma R., Acoustic Studies of copper soap urea complexes derived from groundnut and sesame oils. J. Phy. Stud. 21(4) (2017) 4601-6.
- Punitha S. and Uvarani R., Physico-chemical studies on some saccharides in aqueous cellulose solutions at different temperatures- acoustical and FTIR analysis. J. Saudi Chem. Soc. 18 (2014) 657-665.
- Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of copper soaps urea complexes derived from mustard and soyabean oils. J. Phy. Sc. 29(3) (2018) 67-82.
- Masson D.O., Solute molecular volumes in relation to solvation an ionization, Philos. Mag. 8 (1929) 218-235.
- Kagathara V.M., Sanariya M.R. and Parsania P.H., Sound velocity and molecular interaction studies on chloroepoxy resins solutions at 30°C, Eur. Polym. J. 36 (2000) 2371-2374.
- Dash A.K. and Paikaray R., Acoustical study on ternary mixture of dimethyl acetamide (DMAC) in diethyl ether and isobutyl methyl ketone at different frequencies, Phys. Chem. Liq. 51(6) (2013) 749-763.
- Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of Cu (II) Soaps derived from mustard and soybean oils. J. Pure Appl. Ultrason. 39(3) (2017) 92-99.
- Singh S. and Bahadur I., Density and speed of sound of 1-ethyl-3-methylimidazolium ethylsulphate with acetic or propionic acid at different temperatures, J. Mol. Liq. 199 (2014) 518-523.